MIXED COMPLEX COMPOUNDS OF PALMITATE, OLEATE CALCIUM WITH ACETAMIDE, NICOTINAMIDE AND THIOCARBAMIDE

Authors

IBADULLAEVA Tursunoy, Institute of General and Inorganic ChemistryFollow
AZIZOV Tokhir, Institute of General and Inorganic ChemistryFollow
IBRAGIMOVA Мavluda, Institute of General and Inorganic ChemistryFollow

DOI

10.51348/FZEA2020

Abstract

The purpose of the study was the synthesis and study of the structure of mixed complexes of palmitate, calcium oleate with acetamide, nicotinamide and thiocarbamide. The mixed coordination compounds of palmitate and calcium oleate were synthesized. The composition, individuality, thermal behavior, methods of coordinating the palmitate and oleate fragments, acetamide, nicotinamide and thiocarbamide molecules have been established. Comparison of the diffraction patterns of calcium palmitate and oleate, free ligand molecules and synthesized compounds showed the mismatch of the diffractograms, conseqently that the synthesized complexes have an individual crystal lattice different from the starting materials. The method of coordination of amide molecules, the environment of the central ion, are proved by IR spectroscopy. Acetamide molecules are coordinated with the central atom through an oxygen atom, thiocarbamide and nicotinamide molecules are coordinated through sulfur and nitrogen atoms, respectively, palmitate and oleate fragments coordinate bidentantly.

Recommended Citation

Tursunoy, IBADULLAEVA; Tokhir, AZIZOV; and Мavluda, IBRAGIMOVA (2020) "MIXED COMPLEX COMPOUNDS OF PALMITATE, OLEATE CALCIUM WITH ACETAMIDE, NICOTINAMIDE AND THIOCARBAMIDE," CHEMISTRY AND CHEMICAL ENGINEERING: Vol. 2020: No. 3, Article 8.
DOI: 10.51348/FZEA2020
Available at: https://cce.researchcommons.org/journal/vol2020/iss3/8