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CHEMISTRY AND CHEMICAL ENGINEERING

Abstract

The aim of the work is to develop a synthesis procedure and obtain new complex compounds of transition metal acetates with 2-aminobenzimidazole (L), to study the composition and structure of the synthesized compounds by elemental, thermal, X-ray phase analysis and IR spectroscopy. A procedure for the synthesis of new complex compounds of Mn(II), Cо(II), Ni(II), Cu(II) and Zn acetates with 2-aminobenzimidazole was developed and the composition and structure of the synthesized complex compounds were studied using modern physicochemical methods. Coordination competing donor centers, electronic and geometric structures of the ligand molecule were studied on the basis of a quantum-chemical calculation of the Gaussian09 LanL2DZ software package. It was shown that during the formation of a metal complex, the 2-aminobenzimidazole ligand is coordinated via a localized nitrogen atom of the imidazole ring

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