Abstract
The aim of this work is the synthesis of iodine N,N-diallylphthalimide and the study of its radical polymerization. In this regard, the synthesis of iodine N,N-diallylphthalimide was carried out in two stages: at the first stage, phthalic anhydride reacts with allylamine and forms allyl phthalimide, at the second stage, allyl phthalimide reacts with allyl iodide to form iodine N, N-diallyl phthalimide. Radical polymerization of the synthesized quaternary salt of N, N-diallyl phthalimide was studied in the presence of the initiator dinitrile azobisisobutyric acid at relatively low temperatures. Kinetic features of the polymerization reaction of iodine N, N-diallyl phthalimide were considered. The reaction order concerning the monomer and initiator was determined to be 1.7 and 0.5, respectively. UV spectroscopic data have established that the polymerization process of iodine N, N-diallyl phthalimide at low temperatures occurs via a donor-acceptor initiation mechanism.
Recommended Citation
MAKSUMOVA, Oytura S.; PULATOVA, Feruza A.; TURSUNOVA, Dilnozakhon I.; and MAKHMUDOVA, Feruza A.
(2025)
"SYNTHESIS AND RADICAL POLYMERIZATION OF N,N-DIALLYL PHTHALIMIDE,"
CHEMISTRY AND CHEMICAL ENGINEERING: Vol. 2025:
No.
2, Article 7.
DOI: https://doi.org/10.70189/1992-9498.1676
Available at:
https://cce.researchcommons.org/journal/vol2025/iss2/7